The correct option is D Haploid spermatozoan with haploid ovum to form diploid zygote
Fertilization is the process of fusion of a haploid sperm (spermatozoan) with a haploid ovum. During this process, the diploid cell is formed called as a zygote. A zygote is the initial stage of formation of multicellular organisms. Thus, the correct answer is option D.