Figure below shows two paths that may be taken by a gas to go from a state A to a state C.
In process AB, 400 J of heat is added to the system and in process BC, 100 J of heat is added to the system. The heat absorbed by the system in the process AC will be :
460 J
See figure alongside
Process AB is isochoric so no work is done.
Heat added to be system is Q = 400 J.
Q=ΔU+ΔW
where ΔU is the change in internal energy ΔW is the work done.
Since ΔW=0
ΔU=Q=400J
Change in internal energy is 400 J.
Process BC is isobaric and the work done is given by
ΔW=P(V2−V1)=6×104(4×10−3−2×10−3
=6×104×2×10−3=120J
Heat added to be system is Q = 100 J.
Since Q=ΔU+ΔW
∴ΔU=Q−ΔW=(100−120)J=−20J
Change in internal energy is - 20 J.
Total increase in internal energy is going from state A to state C is 400 - 20 = 380 J
Work done in process AC is the area under the curve.
Area of the trapezium =12(P2+P1)×(V2+V1)
=12(6×104+2×104)×(4×10−3−2×10−3)
=12×8×104×2×0−3=80J.
Since Q=ΔU+ΔW
and ∆U the change in internal energy in process AC, we have
ΔU=380JandΔW=80J
∴Q=ΔU+ΔW=380+80=460J