Preposition 'of' is used with measurements and expressions of time, age, money, amount, etc. Here, we need a preposition that connects 'cheque' with 'a hundred pounds.' So, Option D is the correct answer as ‘of’ is used with cheque to imply that the cheque concerns the amount of a hundred pounds. Prepositions in Options A, B and C would not bring out the intended meaning of the sentence and their usage in the sentence would be incorrect.