Electron affinity:
- The amount of energy released while converting a neutral gaseous isolated atom into a negatively charged gaseous ion/anion by the addition of an electron is called electron affinity (E.A.).
- On moving from left to right in a period of the periodic table, the atomic size decreases, and the nuclear charge increases. Thus, the electron affinity increases.
- On moving down the group in the periodic table, the atomic size increases, and the nuclear charge decreases. Thus, the electron affinity decreases.
Electron affinities of Halogens:
- As all the halogen atoms lack only 1 electron in their valence shell to achieve the stable completely filled electronic configuration, thus they readily accept the additional electron to achieve that stable configuration.
- When the stability of an atom is achieved and forms an anion then the energy released is known as electron affinity.
- Halogens are said to have the highest electron affinities as they are just short of 1 electron to achieve the stable configuration and thus readily accept that electron.
Hence, Halogens have high Electron Affinity.