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Question

Find moles of N2O4 and NO2 at equilibrium are 1 and 2 respectively total pressure at equilibrium is 9 atm. Find KP for the reaction N2O4(g)2NO2(g).

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Solution

N2O4(g)2NO2(g)
1 2
total pressure (P) = 9 atm
Kp=(PNO2)2PN2O4(1)
PNO2=YNO2Ptotal (from Dalton's law)
where, YNO2= mole fraction of NO2
PNO2=(21+2)×9=23×9=6atm(2)
and PN2O4=13×9=3atm(3)
from (1), (2) and (3) we have
Kp=623=6×63=12

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