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Question

Find out number of reagents which can oxidise ethanal.
i) I2/NaOH ii) CrO3
iii) Tollens' reagent iv) LiAIH4
v) NaBH4 vi) mCPBA
vii) SeO2/Δ viii) NH2NH2/pH(46)

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Solution

i) CH3CHOI2/NaOH−−−−−−−−−Indoform reactionCHI3+HO||CO

(ii) CH3CHOCrO3−−CH2COOH

(iii) CH3CHOTollens−−−−ReagentsCH3COOH

(vi) CH3CHOmCPBA−−−−CH3COOH

(vii) CH3CHOSeO2, Δ−−−−HO||CO||CH

Hence here five reagents can oxidise CH3CHO.

LiAIH4,NaBH4 and NH2NH2/pH(46) are reducing agent hence it can not oxidise.

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