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Question

Find out the heat evolved in combustion if 112 litres(at STP) od water gas (mixture of equal volue of H2(g) and CO(g)
H2(g)+1/2O2(g)H2O(g) ΔH=241.8kJ
CO(g)+1/2O2(g)CO2(g) ΔH=283kJ

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Solution

ΔHrxn=ΔHreactantcombustionΔHproductcombustion
Volume of H2=56 litres= Volume of CO (given)
Moles of H2= Moles of CO=5622.4=2.5 moles
For H2, H2(g)+12O2(g)H2O(g)
ΔH=241.8 kJ/mol1
5×241.8=5×ΔHH2combustion
ΔHH2combustion=241.8 kJ/mol
For 2.5 moles=604.5 kJ
Similarly,
ΔHCO2combustion=283 kJ/mol
For 2.5 moles=707.5
Total energy released =707.5604.5=1312 kJ

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