Find out the internal energy change for the reaction A(l)→A(g) at 373K. Heat of vaporisation is 40.66kJ/mol and R=8.3Jmol−1K−1.
A
50.56kJmol−1
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B
22.56kJmol−1
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C
37.56kJmol−1
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D
45.56kJmol−1
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Solution
The correct option is C37.56kJmol−1 Given : A(l)→A(g)so,Δng=np−nr=1−0=1 ΔH=ΔU+ΔngRT ΔU=ΔH−ΔngRT =40660−1×8.3×373=40660−3095.9=37564J/mol ΔU=37.56kJmol−1