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Question

Find out the internal energy change for the reaction A(l)A(g) at 373 K. Heat of vaporisation is 40.66 kJ/mol and R=8.3 Jmol1K1.

A
50.56 kJmol1
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B
22.56 kJmol1
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C
37.56 kJmol1
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D
45.56 kJmol1
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Solution

The correct option is C 37.56 kJmol1
Given :
A(l)A(g)so, Δng=npnr=10=1
ΔH=ΔU+ΔngRT
ΔU=ΔHΔngRT
=40660 1×8.3×373=406603095.9=37564 J/mol
ΔU=37.56 kJmol1

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