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Question

Find oxidation state of N in HNO3


A

+2

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B

-3

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C

+3

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D

+5

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Solution

The correct option is D

+5


Here,The oxidation number of N will not be +3 of -3 why? Let's check it out

Structure of HNO3 is

O. N. of H = +1

O.N. of N = (covalent bond with OH)+(Covalent bonds with O)+(coordinate covalent bond with O)

= (+1 + (+2) + (+2) [Because N is less E.N. than O] = +5

Alternatively :

O. N. of H = +1

O.N. of O = - 2

(+1) +N +3 (-2) =0

n = 5


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