The correct option is B 64%
The approximate percentage composition of oxygen by mass in the compound HClO4 is 64%.
The atomic masses (in g/mol) of H, Cl and O are 1, 35.5 and 16 respectively.
Molar mass of HClO4=1+35.5+4(16)=100.5 g/mol.
Mass of O present in 1 mole of HClO4=6(16)=64 g.
Percent composition of oxygen =64×100100.5≃64%.