Find the correct statement(s) with respect to the following reaction sequence:

P is an optically active isocyanate

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Q is

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R is

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R is

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Solution

The correct options are
A P is an optically active isocyanate
D R is

In Curtius rearrangement, there is a retention of the configuration.

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(C_{9} H_{12}) i) O_{2} - ---- \to i i) H_{3} O^{+} P C H C l_{3} / N a O H - -------- \to Q (m a j o r) + R (m i n o r) Q N a O H - ----- \to P h C H_{2} B r S

C u m e n e (C_{9} H_{12}) i) O_{2} - ----- \to i i) H_{3} O^{+} P C H C l_{3} / N a O H - -------- \to Q (m a j o r) + R (m i n o r)

Q N a O H - ----- \to P h C H_{2} B r S

Cumene (C_{9} H_{12}) (i) O_{2} - ----- \to (i i) H_{3} O^{+} P + Acetone

P i . C H C l_{3} / N a O H - --------- \to i i . H^{+} / H_{2} O Q (major) + R (minor) Q P h C H_{2} B r - ----- \to N a O H S

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