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Question

Find the number of acid(s) which are having peroxy linkage from the following:
H3PO5,H2SO5,H2S2O7,H2S2O8,HClO4

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Solution

Three acids have peroxy linkage.
H3PO5: Peroxomonophosphoric acid, (OP(OH)2(OOH)), a tribasic acid containing a peroxide group.
H2SO5: Peroxomonosulphuric acid contains an O-O linkage.
H2S2O7: Pyrosulphuric acid does not contain an O-O linkage.
H2S2O8: Peroxodisulphuric acid contains an O-O linkage.
HClO4: Perchloric acid does not contain an O-O linkage.

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