Following four reactions are involved in roasting process.
(i)S8+8O2Δ−→8SO2↑
(ii) P4+5O2Δ−→P4O10↑
(iii) 4As+3O2Δ−→2As2O3↑
(iv)2ZnS+3O2Δ−→2ZnO+2SO2↑
Note: During roasting the ore is heated in excess of air to convert metals into their oxides and water insoluble sulphides into water soluble sulphates.