Find the number of ligand (s) in which the donor atom is only $N .$

[NH $_{2}$ CH $_{2}$ COO $^{Θ}$ , en, dien, Py, EDTA]

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Solution

In three ligands (en, dien and Py) the donor atom is only N.

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_{3}

e n

C l^{-}

_{3}

^{-}

C N^{-}

(N H_{2}^{-}, C H_{3} C O O^{-}, O H^{-})

(N O ⊖ S)

S O_{4}^{2 -},

P P h_{3}

H_{3} N^{+} - (C H_{2})_{4} C H (N H_{3}^{+}) C O O H p K = 2.2 ⇌ H_{3} N^{+} - (C H_{2})_{4} C H (N H_{3}^{+}) C O O^{-} + H^{+}

H_{3} N^{+} - (C H_{2})_{4} C H (N H_{2}) C O O^{-} + H_{2} O p K = 5 ⇌ H_{3} N^{+} - (C H_{2})_{4} C H (N H_{3}^{+}) C O O^{-} + O H^{-}

H_{2} N - (C H_{2})_{4} C H (N H_{2}) C O O^{-} + H_{2} O p K = 3.4 ⇌ H_{3} N^{+} - (C H_{2})_{4} C H (N H_{2}) C O O^{-} + O H^{-}

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