Find the number of sodium and sulphate ions in 14.2g of sodium sulphate.
Now, for every 1 mol of Na_2 ,SO_4 you have 2 moles of Na^+ ions. Multiple the moles of Na_2 ,SO_4 that you found just then by 2 to obtain the moles of sodium ions.
Use Avogadro's number (6.022 x 10^23) to find the number of ions present. (Recall that Avogrado's number is the number of particles per mole of a substance).
6.022 x 10^23 x 0.2 mol = 1.2044 x 10^23ions