The correct option is C I, II and III
When I, II and III are placed into water will test as an acid solution.
I. HCl(g)+H2O is an acidic solution as hydrochloric acid completely ionizes and gives hydrogen ions in solution.
II. Excess H3O+ +H2O is acidic in nature as a solution has more number of hydronium ions than hydroxide ions.
III. CuSO4(s) +H2O solution is acidic in nature as copper sulphate is a salt of a weak base with a strong acid.