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Question

Find the sum of bond order and the number of π - bonds in C2 molecule on the basis of molecular orbital theory.

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Solution

C2 has 12 electrons.
(σ1s)2,(σ1s)2,(σ2s)2,(σ2s)2,(π)4
So, Bond Order=12(ab)
Here, a is the number of electrons in bonding molecular orbitals and b is the number of electrons in antibondng molecular orbitals.
Bond Order=12(84)=2
Number of pi bonds in C2 is 2.
Therefore, sum is 2+2=4

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