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Structural Isomerism

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Question

Find the total number of possible isomers (cis-trans and optical) of CrCI $_{2}$ en $_{2}^{+}$ .

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Solution

The total number of possible isomers (cis-trans and optical) of CrCI $_{2}$ en $_{2}^{+}$ is 3. Trans isomer is optically inactive whereas cis isomer is optically active and exists in d and l forms.

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Q. Which of the following will show optical isomers?
(I)

C i s - [C o (N H_{3})_{2} (e n)_{2}]^{3 +}

T r a n s - [I r C l_{2} (C_{2} O_{4})_{2}]^{3 -}

[R h (e n)_{3}]^{3 +}

c i s - [I r (H_{2} O)_{3} C l_{3}]

.

Q. Which of the following statements is not true about the complex ion

[P t (e n)_{2} C l_{2}]^{2 +}

?

Q. Assertion :trans-pent-2-ene is polar but trans-but-2 -ene is non-polar. Reason: The probability of cis-isomer is more than trans-isomers, which is either non-polar or less polar.

[C o (N H_{3}) C l (e n)_{2}]^{2 +}

shows two geometrical isomers cis and trans. Which of the following statements is correct?

Q. For the given complex

{[C o {C l}_{2} (e n) {({N H}_{3})}_{2}]}^{+}

, the number of geometrical isomers, the number of optical isomers and total number of isomers of all type possible respectively are:

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