Multi-Electron Configurations and Orbital Diagrams
Find the two ...
Question
Find the two longest wavelengths( in ˚A) emitted when hydrogen atoms make transitions and the spectral lines lie in the visible region (R = 1.097 × m−1).
A
6562.8 ˚A, 4861.3 ˚A
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B
6662.8 ˚A, 4761.3 ˚A
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C
6762.8 ˚A, 4661.3 ˚A
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D
6962.8 ˚A, 4361.3 ˚A
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Solution
The correct option is A 6562.8 ˚A, 4861.3 ˚A As we know, Longest λ = Shortest energy gap In visible region, 3 → 2 and 4→ 2 are the two longest wavelengths λ3→2 = 6562.8 A λ4→2 = 4861.3 A so these are the longest wavelengths.