Dear student,
1. Methyl alcohol and water are miscible liquids with boiling points as 780 C and 1000C respectively. Methyl alcohol with lower boiling point is more volatile than water. So, it gets collected in collection flask as a distillate while water condenses in the flask.
2. kerosene oil in water,
3. coconut oil in water,
4. mustard oil in water
5. any alcohol in water
Regards