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Question

Flourobenzene (C6H5F) can be synthesised in the laboratory :

A
by heating phenol with HF and KF
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B
from aniline by diazotisation followed by heating the diazonium salt with HBF4
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C
by direct fluorination of benzene with F2 gas
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D
by reacting PhBr with NaF solution
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Solution

The correct option is D from aniline by diazotisation followed by heating the diazonium salt with HBF4

Fluorobenzene (C6H5F) can be synthesized in the laboratory from aniline by diazotisation followed by heating the diazonium salt with HBF4. The reaction is called Balz-Schiemann reaction.
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