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Question

Following are the thermochemical reactions:
C (graphite) +12O2CO ;ΔH=110.5 kJ/mol
CO+12O2CO2 ;ΔH=283.2 kJ/mol

The heat of reaction (in kJ/mol) for the following reaction is:
C(graphite)+O2CO2

A
+393.7
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B
393.7
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C
172.7
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D
+172.7
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Solution

The correct option is B 393.7
The thermochemical reactions are as given below:
C (graphite) +12O2CO;ΔH=110.5 kJ/mol ...(1)
CO+12O2CO2;ΔH=283.2 kJ/mol ......(2)
The above two reactions are added to obtain the following reaction:
C (graphite) +O2CO2
By applying Hess's law, the enthalpy change will be 110.5+(283.2)=393.7 kJ/mol
Hence, the heat of the given reaction is 393.7 kJ/mol.

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