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Question

Following experiment is designed to determine calcium content in the blood. Read the experiment and answer the questions at the end of it.
Calcium oxalate (CaC2O4) is insoluble in water. For this reason, it can be used to determine the amount of Ca2+ ions in fluids such as blood. The calcium oxalate isolated from blood is dissolved in acid and titrated against a standardized KMnO4 solution.
Calcium content expressed in ppm is 250.

A
True
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B
False
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Solution

The correct option is A True
25 mL of 1×103M MnO4 =25 mL of 5×103N MnO4
=0.125 milliequivalents of MnO4
=0.125 milliequivalents of CaC2O4
=0.125 milliequivalents of Ca2+
=0.125×20 mg of Ca2+ in 10 mL
=0.250 mg/mL =0.250 g/L =250 ppm

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