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Question

For a certain reaction, ΔH0 and ΔS0 respectively are 400 kJ and 200 J/Mole/K. The process is non-spontaneous at:

A
2100 K
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B
2010 K
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C
1990 K
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D
2020 K
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Solution

The correct option is B 1990 K
ΔG0=ΔH0TΔS0
Just non- spontaneous means ΔG0=0
Hence,
ΔH0 = TΔS0
T=400×103200 =2000 K
Hence, for non-spontaneous, correct T among above is 1990K.

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