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Byju's Answer
Standard XI
Chemistry
Gibbs Free Energy & Spontaneity
For a given c...
Question
For a given chemical reaction
A
→
B
at
300
K
the free energy change is
−
49.4
k
J
m
o
l
−
1
and the enthalpy of reaction is
51.4
k
J
m
o
l
−
1
. The entropy change of the reaction is _____
J
K
−
1
m
o
l
−
1
.
(JEE Main 2021)
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Solution
Δ
G
=
−
49.4
k
J
/
m
o
l
Δ
H
=
51.4
k
J
/
m
o
l
Δ
G
=
Δ
H
−
T
Δ
S
−
49400
=
51400
−
300
Δ
S
Δ
S
=
+
100800
300
=
336
J
K
−
1
m
o
l
−
1
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0
Similar questions
Q.
For a given chemical reaction
A
→
B
at
300
K
the free energy change is
−
49.4
k
J
m
o
l
−
1
and the enthalpy of reaction is
51.4
k
J
m
o
l
−
1
. The entropy change of the reaction is _____
J
K
−
1
m
o
l
−
1
.
Q.
The enthalpy change for a certain reaction at 300 K is -15.0 Kcal mol
−
1
. The entropy change under these conditions is -7.2 cal K
−
1
mol
−
1
. The free energy change for the reaction and its spontaneous/nonspontaneous character will be:
Q.
For the reaction NH4Cl (s) NH3 (g) + HCL (g) at 25 , enthalpy change DH = +177 kJ per mole and entropy change triangle DS = +285 JK
-1
mol
-1
.Calculate free energy change DG at 25°C and predict whether the reaction is spontaneous or not.
Q.
For the reaction
N
H
4
C
l
(
S
)
→
N
H
3
(
g
)
+
H
C
l
(
g
)
at
25
0
C, enthalpy change
△
=
+
177
k
J
m
o
l
−
1
and entropy change
△
S
=
+
285
J
K
−
1
m
o
l
−
1
. Calculate free energy change
△
G
at
25
0
C and product whether the reaction is spontaneous or not.
Q.
The standard entropy change for the reaction
4
F
e
(
s
)
+
3
O
2
(
g
)
→
2
F
e
2
O
3
(
s
)
is
–
550
J
K
–
1
at
298
K
.
[Given: The standard enthalpy change for the reaction is
–
165
k
J
m
o
l
–
1
]
. The temperature in
K
at which the reaction attains equilibrium is
. (Nearest Integer)
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