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Question

For a reaction,4M(s)+nO2(g)2M2On(s) the free energy change is plotted as a function of temperature. The temperature below which the oxide is stable could be inferred from the plot as the point at which


A

The free energy change shows a change from negative to positive value.

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B

The slope changes from positive to zero.

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C

The slope changes from positive to negative.

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D

The slope changes from negative to positive.

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Solution

The correct option is A

The free energy change shows a change from negative to positive value.


Explanation for the correct option:

A) the free energy change shows a change from a negative to a positive value.

  • According to the Ellingham plot, it is a curve that denotes the reaction between Gibbs energy and temperature G=H-TS.
  • The curve line of the diagram shows the stability of the compound. The slope of the reaction is a straight line but the temperature at which the phase changes lead to a positive increase.
  • When the value of it forms stable oxide while the +veG forms unstable oxide.
  • So, option A is correct the free energy change shows a change from negative to a positive value.

Explanation for the incorrect options:

B) The above explanation clearly shows that slope change indicates the temperature at which phase of the chemical reaction changes and the slope can't change from positive to zero. Hence option B is incorrect.

C)The above explanation clearly shows that slope change indicates the temperature at which phase of the chemical reaction changes and the slope can't change from positive to negative. Hence option C is incorrect.

D)The above explanation clearly shows that slope change indicates the temperature at which phase of the chemical reaction changes and the slope can't change from negative to positive. Hence option D is incorrect.


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