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Question

For a saturated solution of AgCl at 250C,K=3.4×106ohm1cm1 and that of H2O(l) used is 2.02×106ohm1.λ0m for AgCl is 138 ohm1cm2mol1.

The solubility of AgCl in moles per liter is a ×105. Find a.

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Solution

For a saturated solution of AgCl at 250C,
λ0=1000×(KsolKH2O)S
138=1000×(3.42.02)×106S
S=1×105

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