The correct option is A ψw=ψs
Free energy is the potential to do work and the free energy of water is 'water potential', given by
ψw=ψs+ψp, where
ψs= solute potential
ψp= pressure potential
At atmospheric pressure, there is no net hydrostatic pressure of the solution.
∴ The pressure potential at atmospheric pressure is zero.
∴ψw=ψs