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Question

For a solution at atmospheric pressure :

A
ψw=ψs
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B
ψw=0
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C
ψs=0
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D
None of above
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Solution

The correct option is A ψw=ψs
Free energy is the potential to do work and the free energy of water is 'water potential', given by
ψw=ψs+ψp, where
ψs= solute potential
ψp= pressure potential
At atmospheric pressure, there is no net hydrostatic pressure of the solution.
The pressure potential at atmospheric pressure is zero.
ψw=ψs

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