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Question

For a spontaneous process, the correct statement(s) is(are)

A
(ΔGsystem)T,P>0
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B
(ΔSsystem)+(ΔSsurroundings)>0
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C
(ΔGsystem)T,P<0
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D
(ΔUsystem)T,V>0
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Solution

The correct options are
B (ΔSsystem)+(ΔSsurroundings)>0
C (ΔGsystem)T,P<0
For a process to be spontaneous,
ΔSsystem+ΔSsurrounding>0
(ΔGsystem)T,P<0
(ΔUsystem)T,V<0
Spontaneity of the process can be expressed either by taking entropy changes of system and surrounding together or by considering free energy changes of the system alone at constant temperature and pressure.

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