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Question

For an elementary reaction 2A+BA2B,
if the volume of the vessel is quickly reduced to half of its original volume, then the rate of the reaction will:

A
Be unchanged
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B
Increase by four times
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C
Increase by eight times
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D
Decrease by eight times
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Solution

The correct option is C Increase by eight times
The rate of the reaction is
r=k[A]2[B]
When the volume will be reduced to half, then rate of the reaction will be
r1=k[2A]2[2B]=8k[A]2[B]=8r
So the rate increases by 8 times

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