For Association Van’t Hoff factor is

i = 0

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i > 1

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i < 1

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i = 1

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Solution

The correct option is C i < 1
In association as particles combine each other , final number of particles are less than intial number of particles. So as
Van't hoff factor = $\frac{N o . o f . P a r t i c l e s f i n a l l y i n t h e s o l u t i o n}{N o . o f p a r t i c l e s i n t i a l l y t a k e n} < 1.$

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