For CO, isotherm is of the type as shown.Near the pointA , compressibility factor Z is

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Solution

The correct option is D

$(V - b) \approx V$
$∴ (p + \frac{a}{V^{2}}) V = R T$
$p V + \frac{a}{V} = R T$
$Z = \frac{p V}{R T} = (1 - \frac{a}{R T V})$

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