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Byju's Answer
Standard XII
Chemistry
Equilibrium Constant from Nernst Equation
For hydrogen-...
Question
For hydrogen-oxygen fuel cell, the cell reaction is:
2
H
2
(
g
)
+
O
2
(
g
)
⟶
2
H
2
O
(
l
)
If
Δ
G
o
f
(
H
2
O
)
=
−
237.2
k
J
m
o
l
−
1
, then emf of this cell is:
A
+
2.46
V
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B
−
2.46
V
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C
+
1.23
V
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D
−
1.23
V
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Solution
The correct option is
A
+
1.23
V
Gibbs free energy,
Δ
G
o
=
−
n
F
E
o
∴
E
o
=
Δ
G
o
n
F
=
237.2
×
1000
J
2
×
96500
=
1.23
V
[
∵
n
=
2
]
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Similar questions
Q.
For a cell reaction,
2
H
2
(
g
)
+
O
2
(
g
)
→
2
H
2
O
(
l
)
△
S
0
298
=
−
0.32
kJK
−
1
. What is the value of
△
f
H
0
298
(
H
2
0
,
l
)
Given :
O
2
(
g
)
+
4
H
+
(
a
q
)
+
4
e
−
→
2
H
2
0
(
l
)
;
E
0
=
1.23
V
Q.
For a cell reaction
2
H
2
(
g
)
+
O
2
(
g
)
⟶
2
H
2
O
(
l
)
;
△
r
S
∘
298
=
−
0.32
k
J
/
K
. What is the value of
△
f
H
∘
298
(
H
2
O
,
l
)
?
Given
O
2
(
g
)
+
4
H
+
(
a
q
.
)
+
4
e
−
⟶
2
H
2
O
(
l
)
;
E
∘
=
1.23
V
Q.
The value of
Δ
S
⊖
for the fuel cell reaction at 298 K is:
2
H
2
+
O
2
→
2
H
2
O
E
⊖
c
e
l
l
=
1.23
V
Δ
f
H
⊖
(
H
2
O
)
=
−
285.8
K
j
m
o
l
−
1
Q.
Hydrazine can be used in fuel cell
N
2
H
4
(
a
q
)
+
O
2
(
g
)
→
N
2
(
g
)
+
2
H
2
O
(
l
)
If
Δ
G
0
for this reaction is -600 kJ, what will be the
E
0
for the cell?
Q.
In a hydrogen oxygen fuel cell, electricity is produced. In this process
H
2
(
g
)
is oxidised at anode and
O
2
(
g
)
reduced at cathode. Given : Cathode:
O
2
(
g
)
+
2
H
2
O
(
l
)
+
4
e
−
→
4
O
H
−
(
a
q
)
Anode :
H
2
(
g
)
+
2
O
H
−
(
a
q
)
→
2
H
2
O
(
l
)
+
2
e
−
4.48
L
of
H
2
at
1
atm
and
273
K
is oxidised in
9650
sec
.
If current produced in fuel cell, use for the deposition of
C
u
2
+
in
1
L
,
2
M
C
u
S
O
4
(
aq
)
solution for
241.25
sec
using
P
t
electrode. The
p
H
of solution after electrolysis is:
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