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Question

For hydrogen-oxygen fuel cell, the cell reaction is:


2H2(g)+O2(g)2H2O(l)

If ΔGof(H2O)=237.2 kJmol1, then emf of this cell is:

A
+2.46V
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B
2.46V
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C
+1.23V
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D
1.23V
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Solution

The correct option is A +1.23V
Gibbs free energy, ΔGo=nFEo

Eo=ΔGonF

=237.2×1000J2×96500

=1.23V[n=2]

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