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Question

For reaction PCl3(g)+Cl2(g)PCl5(g),Kc is 30 at 300 K. The value of Kp at 300 K is

A
1.219
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B
2.43
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C
3.67
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D
None of these
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Solution

The correct option is A 1.219
For a gaseous reaction 2BA, the equilibrium constant Kp is less than Kc
Kp=Kc(RT)Δn
Δn=12=1
Kp=Kc(RT)1
KP<Kc
here, KP=30/3000.083=1.2

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