For silver, Cp(JK−1mol−1)=23+0.01T. If the temperature (T) of 3 moles of silver is raised from 300 K to 1000 K at 1atm pressure, the value of ΔH will be close to:
Given: n = 3
T1=300;T2=1000
Cp=23+0.01T
ΔHandCp
ΔH=T2∫T1nCpdT
=ΔH=n1000∫300(23+0.01T)dT
=3[23(1000−300)[+0.012(10002−3002)]]
=3[16100+4550]
=3×20650=61950 J
≈62 kJ