Given: The equation of electron capture process is e + + X Z A → Y Z−1 A +ν
The nuclear reaction can be written as,
e + + X Z A → Y Z−1 A +ν+ Q 1
where, the amount of energy released during the electron capture process is Q 1 .
The nuclear reaction during the positron capture process can be written as,
X Z A → Y Z−1 A +ν+ e + + Q 2
where, the amount of energy released during the positron capture process is Q 2 .
The Q− value of the electron capture reaction can be written as,
Q 1 =[ m N ( X Z A )+ m e − m N ( Y Z−1 A ) ] c 2 =[ m A ( X Z A )−Z m e + m e − m A ( Y Z−1 A )+( Z−1 ) m e ] c 2 =[ m A ( X Z A )− m A ( Y Z−1 A ) ] c 2 (1)
where, the nuclear mass of X Z A is m N ( X Z A ), the nuclear mass of Y Z−1 A is m N ( Y Z−1 A ), the atomic mass of X Z A is m A ( X Z A ), the atomic mass of Y Z−1 A is m A ( Y Z−1 A ), the speed of light is c, and mass of an electron is m e
The Q− value of the positron capture reaction can be written as,
Q 2 =[ m N ( X Z A )− m N ( Y Z−1 A )− m e ] c 2 =[ m A ( X Z A )−Z m e − m A ( Y Z−1 A )+( Z−1 ) m e − m e ] c 2 =[ m A ( X Z A )− m A ( Y Z−1 A )−2 m e ] c 2 (2)
From equation (1) and (2),
Q 2 >0 , then Q 1 >0
Thus, it is shown that, if Q 2 >0 then Q 1 >0 and, if Q 1 >0 then it is not necessary that Q 2 >0.