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Question

For the cell prepared from electrode A and B, electrode A: Cr2O2−7Cr3+, E0red=+1.33V and electrode B: Fe3+Fe2+, E0red=0.77V, which of the following statement is not correct?

A
The electrons will flow from B to A (in the outer circuit) when connections are made.
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B
The standard e.m.f. of the cell will be 0.56V
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C
A will be positive electrode
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D
Current flows from B to A in external circuit.
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Solution

The correct option is D Current flows from B to A in external circuit.
(A) The electrons will flow from B to A when
connection are made.
This statement is wrong because electrons will move
from A to B as electrons move from higher potential
+1.33V to the lower potential 0.77V.

1113888_873242_ans_0fff5c8f45e045c5b96961c41b8c3157.jpg

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