For the cell: Tl(s)|Tl+(0.001M)||Cu+2(0.1M)|Cu(s) Ecell=0.83V at 298 K, the cell potential can be increased by
A
Increasing [Cu+2]
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B
Increasing [Tl+]
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C
Decreasing [Cu+2]
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D
Decreasing [Tl+]
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Solution
The correct options are AIncreasing [Cu+2] DDecreasing [Tl+] Cell reaction is 2Tl(s)+Cu+2(aq)⇌2Tl+(aq)+Cu(s) Qc=[Tl+]2[Cu+2] E=E0−0.0591nlogQcat298K E=E0−0.0591nlog([Tl+]2[Cu+2])