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Question

For the cell:
Tl(s)|Tl+(0.001 M)||Cu+2(0.1 M)|Cu(s)
Ecell=0.83 V at 298 K, the cell potential can be increased by

A
Increasing [Cu+2]
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B
Increasing [Tl+]
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C
Decreasing [Cu+2]
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D
Decreasing [Tl+]
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Solution

The correct options are
A Increasing [Cu+2]
D Decreasing [Tl+]
Cell reaction is
2Tl(s)+Cu+2(aq)2Tl+(aq)+Cu(s)
Qc=[Tl+]2[Cu+2]
E=E00.0591nlogQcat298K
E=E00.0591nlog([Tl+]2[Cu+2])

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