For the cell: Tl(s)|Tl+(0.001M)||Cu2+(0.1M)|Cu(s): Ecell= 0.83 V at 298 K, The cell potential can be increased by
A
increasing[Cu2+]
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B
increasing[Tl+]
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C
decreasing[Cu2+]
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D
decreasing[Tl+]
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Solution
The correct options are Aincreasing[Cu2+] Ddecreasing[Tl+] The cell reaction is: Tl(s)+Cu2+aq⇌Tl+aq+Cu(s) Qc=Tl+Cu2+ E=E0−0.0591nlogQcat298k E=E0−0.059nlog([Tl+][Cu2+])