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Question

For the cell:

Tl(s)/Tl+ (0.001M)// Cu+2(0.1M)/Cu(s):

Ecell​ = 0.83V at 298K, The cell potential can be increased by


A

Increasing

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B

Increasing

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C

Decreasing

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D

Decreasing

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Solution

The correct options are
A

Increasing


D

Decreasing


Tl(s) + Cu+2(aq) ⇌​ Tl+(aq)​ + Cu(s)

Qc​= ([Tl+][Cu+2])

E = Eo - (0.0591n)log Qc​​ at 298 K

E = Eo - (0.0591n) log ([Tl+][Cu+2])


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