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Question

For the combustion of 1 mole of liquid benzene at 25oC, the heat of reaction at constant pressure is given by
C6H6(l)+712O2(g)6CO2(g)+3H2O(l); U=780980 cal
What would be the heat of reaction at constant volume?

A
780 kcal
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B
780 kcal
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C
580 kcal
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D
580 kcal
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Solution

The correct option is A 780 kcal
H=Heat of reaction
We have, H=U+ngRT
Here, ng=67.5=1.5
Thus, H=U+ngRT
H=780980+(1.5)×2×298
H=780090 cal=780.090 kcal

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