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Question

For the equilibrium C(s)+CO2(g)2CO(g)Kp=63 atm at 1000K. If at equilibrium P=10Pco2 total pressure at equilibrium is :-

A
6.30 atm
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B
0.693 atm
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C
6.93 atm
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D
69.3 atm
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Solution

The correct option is C 6.93 atm
At equilibrium
C(g)+CO2(g)2CO(g)
Given KP=63
KP=P2COPCO2=(10PCO2)2PCO2=100PCO2PCO2=100PCO2=63
PCO2=63100=0.63atm
PCO=10PCO2=10×0.63atm=6.3atm
Ptot=PCO2+PCO=0.63atm+6.3atm=6.9atm

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