For the equilibrium N2O4(g)⇌2NO2(g). The vapour density at 60∘C was found to be 30.15.The degree of dissociation of N2O4 is
0.525
For an hypothetical reaction
An⇌nA
Degree of dissociation α=D−dd(n−1)
where d = observed vapour density
D = calculated vapour density
For the reaction
N2O4(g)⇌2NO2 ; n=2
DN2O4=molar mass of N2O42=922=46
α=46−301530.15(2−1)=0.525