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Question

For the following reations major products are:

A
P , S , U and W
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B
P , S , U and V
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C
Q , R , T amd W
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D
Q , R , T amd V
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Solution

The correct option is A P , S , U and W
  • these are electrophilic substitution reactions of benzene which follow mechanism
  • so major product from that which have more stable +ve charge at carbon
  • +ve charge is stablised by hyper-conjugation and we know hyperconjugation effect order for CH3>CD3>CT3 so electrophile should attaiched at ortho position to as order preference CH3>CD3>CT3
  • thus correct response of this is P , S , U and W are major products

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