The given quadrilateral is an isosceles trapezoid.
Considering AB as transversal to AD and BC, ∠A and ∠B are supplementary angles.
∴∠A=180o−∠B=72o
An isosceles trapezoid is formed by cutting an isosceles triangle along a line parallel to the side of the triangle connecting the equal angles of the triangle.
That means the non-parallel equal lines of an isosceles trapezoid, when extended, always meet at a point, forming an isosceles triangle. ∴∠A=∠D=72o