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Factors Affecting Alpha

For the given...

Question

For the given reaction,
$P C l_{5} (g) ⇌ P C l_{3} (g) + C l_{2} (g)$
Calculate $K_{p}$ , if at equilibrium $2$ moles each of $P C l_{5}, P C l_{3},$ and $C l_{2}$ is maintained at $250^{o} C$ and a total pressure of $3 atm$ .

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Solution

The correct option is D $1$
$\begin{matrix} P C l_{5} & ⇌ & P C l_{3} & + & C l_{2} A t e q u i l i b r i u m & 2 & 2 & 2 \end{matrix}$
$P_{C l_{5}} = \frac{2}{6} \times 3, P_{P_{C l_{3}}} = \frac{2}{6} \times 3, P_{C l_{2}} = \frac{2}{6} \times 3$
$K_{p} = \frac{p_{P C l_{3}} \times p_{C l_{2}}}{p_{P C l_{5}}} = \frac{1 \times 1}{1} = 1$

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