For the given reaction, which of the following expressions is correct?
BrO−3(aq)+5Br−(aq)+6H+→3Br2(l)+3H2O(l)
A
d[Br2]dt=−d[Br−]dt
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B
d[Br2]dt=+35d[Br−]dt
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C
d[Br2]dt=−35d[Br−]dt
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D
d[Br2]dt=+53d[Br−]dt
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Solution
The correct option is Cd[Br2]dt=−35d[Br−]dt For a reaction: aA→bB a,b are stoichiometric coefficients of reactant A and product B respectively Rate=−1a×d[A]dt=+1b×d[B]dt
So, for the reaction: BrO−3(aq)+5Br−(aq)+6H+→3Br2(l)+3H2O(l)
Writing rate in terms of Br− and Br2 Rate=−15×d[Br−]dt=+13×d[Br2]dt