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Question

For the given reaction, which of the following expressions is correct?

BrO3(aq)+5Br(aq)+6H+3Br2(l)+3H2O(l)

A
d[Br2]dt=d[Br]dt
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B
d[Br2]dt=+35d[Br]dt
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C
d[Br2]dt=35d[Br]dt
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D
d[Br2]dt=+53d[Br]dt
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Solution

The correct option is C d[Br2]dt=35d[Br]dt
For a reaction:
aAbB
a,b are stoichiometric coefficients of reactant A and product B respectively
Rate=1a×d[A]dt=+1b×d[B]dt
So, for the reaction:
BrO3(aq)+5Br(aq)+6H+3Br2(l)+3H2O(l)

Writing rate in terms of Br and Br2
Rate=15×d[Br]dt=+13×d[Br2]dt

d[Br2]dt=35d[Br]dt

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