For the non-zero values of forces of attraction between gas molecules and zero volume occupied by the gas molecules, Van der Waals equation will be:
A
PV=nRT−n2aV
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B
PV=nRT+nbP
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C
PV=nRT
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D
P=nRTV−b
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Solution
The correct option is APV=nRT−n2aV Van der Waals equation for real gas is, (P+n2aV)(V−nb)=nRT
For non zero forces of attraction between gas molecules and zero volume occupied by the gas molecules, a≠0andb=0 Hence, the Van der Waals equation will be, PV=nRT−n2aV