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Question

For the non-zero values of forces of attraction between gas molecules and zero volume occupied by the gas molecules, Van der Waals equation will be:

A
PV=nRTn2aV
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B
PV=nRT+nbP
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C
PV=nRT
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D
P=nRTVb
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Solution

The correct option is A PV=nRTn2aV
Van der Waals equation for real gas is,
(P+n2aV)(Vnb)=nRT

For non zero forces of attraction between gas molecules and zero volume occupied by the gas molecules,
a0 and b=0
Hence, the Van der Waals equation will be,
PV=nRTn2aV

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