For the process, H2O(l)(1bar,373K)→H2O(g)(1bar;373K) The correct set of thermodynamics parameters is:
A
ΔG=0,ΔS=+ve
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B
ΔG=0,ΔS=−ve
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C
ΔG=+ve,ΔS=0
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D
ΔG=−ve,ΔS=+ve
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Solution
The correct option is BΔG=0,ΔS=+ve H2O(l)⇌H2O(g)
It is an equilibrium process.
Therefore, ΔG=0
Now, ΔG=ΔH−TΔS
where ΔH is the enthalpy of vaporization & ΔH>0
Therefore, for ΔG=0, the value of ΔS should be positive. Also, the ΔS is always when a molecule is energized. Here, the liquid H2O is energized to gaseous H2O. So, ΔS is +ve.