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Question

For the process,
H2O(l)(1bar,373K)H2O(g)(1bar;373K)
The correct set of thermodynamics parameters is:

A
ΔG=0,ΔS=+ve
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B
ΔG=0,ΔS=ve
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C
ΔG=+ve,ΔS=0
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D
ΔG=ve,ΔS=+ve
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Solution

The correct option is B ΔG=0,ΔS=+ve
H2O(l)H2O(g)
It is an equilibrium process.
Therefore, ΔG=0
Now, ΔG=ΔHTΔS
where ΔH is the enthalpy of vaporization & ΔH>0
Therefore, for ΔG=0, the value of ΔS should be positive. Also, the ΔS is always when a molecule is energized. Here, the liquid H2O is energized to gaseous H2O. So, ΔS is +ve.

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