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Question

For the process: H2O(l)(1 bar, 373K)H2O(g)(1 bar, 373K) the correct set of thermodynamic parameter is :

A
ΔG=0,ΔS=+ve
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B
ΔG=0,ΔS=ve
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C
ΔG=+ve,ΔS=0
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D
ΔG=ve,ΔS=+ve

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Solution

The correct option is A ΔG=0,ΔS=+ve
Here liq. and vap. phase are in equilibrium therefore ΔU=0. Degree of randomness increases hence ΔS>0

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